I created the shader for the Spider-Clan suit and its outline. It has a thin terminator like a classic toon shader but also uses a combination of light direction and fresnel to mimic the way highlights are applied to characters in the comic.
Character Artist: Dustin Brown
https://www.artstation.com/dustinbrown
Art Direction: Jacinda Chew
https://twitter.com/jacinda_chew
Character TD: Sergio Sykes
https://www.sergiosykes.com
Lead Character Artist: Gavin Goulden
https://www.artstation.com/gavin